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Beilstein J. Org. Chem. 2013, 9, 1620–1629, doi:10.3762/bjoc.9.185
Graphical Abstract
Scheme 1: Experimental results for the radical arylation of epoxides.
Scheme 2: 5-exo cyclization of the hexenyl radical.
Scheme 3: Intramolecular radical additions of simple aniline derivatives.
Scheme 4: Successful catalytic radical addition to an N-methyl substituted aniline.
Figure 1: Optimized structure of the transition state of the radical addition of 1 (left: spin density plot a...
Scheme 5: Intramolecular radical additions of simple aniline derivatives.
Scheme 6: Mismatching of polar effects.
Scheme 7: Examples of p-substituted anilines investigated.
Scheme 8: Examples of m,m’-disubstituted anilines investigated.
Scheme 9: Addition reactions leading to dihydrobenzofuran and an indane.